Tuning anisotropy by impurities : magnetocaloric experiments on
نویسنده
چکیده
The magnetic phase diagram of the Fe doped hexagonal ABX3 compound CsNi0.9Fe0.1Cl3 is investigated by heat capacity and magnetocaloric experiments. In spite of the high doping concentration, some phase boundaries appear surprisingly well-defined, while others are broadened significantly. The discussion of this behaviour clarifies the potentials and limitations of doping as a means to manipulate the effective anisotropy in quasi one-dimensional ABX3 compounds. PACS. 75.30.Sg Magnetocaloric effect, magnetic cooling – 75.30.Kz Magnetic phase boundaries
منابع مشابه
Tuning entanglement and ergodicity in two-dimensional spin systems using impurities and anisotropy
متن کامل
Tuning structural instability toward enhanced magnetocaloric effect around room temperature in MnCo1−xZnxGe
Magnetocaloric effect is the phenomenon that temperature change of a magnetic material is induced by application of a magnetic field. This effect can be applied to environmentally-benign magnetic refrigeration technology. Here we show a key role of magnetic-field-induced structural instability in enhancing the magnetocaloric effect for MnCo(1-x)Zn(x)Ge alloys (x = 0-0.05). The increase in x rap...
متن کاملCrystallography, anisotropic metamagnetism, and magnetocaloric effect in Tb5Si2.2Ge1.8
The metamagnetic-like transitions and giant magnetocaloric effect were observed with the magnetic field applied parallel to the aand c axes, but not the b axis in a Tb5Si2.2Ge1.8 single crystal. The in situ x-ray powder diffraction study indicates that these metamagnetic-like transitions are coupled to crystallographic phase transformations occurring via strong magnetoelastic interactions. The ...
متن کاملMicrostructural Anisotropy of Magnetocaloric Gadolinium Cylinders: Effect on the Mechanical Properties of the Material
The development of advanced materials and technologies based on magnetocaloric Gd and its compounds requires an understanding of the dependency of mechanical properties on their underlying microstructure. Therefore, the aim of the study was to characterize microstructural inhomogeneities in the gadolinium that can be used in magnetocaloric refrigeration systems. Microstructures of magnetocalori...
متن کاملMagnetic field induced phase transitions in Gd5(Si1.95Ge2.05) single crystal and the anisotropic magnetocaloric effect
Magnetization measurements using a Gd5(Si1.95Ge2.05) single crystal with the magnetic field applied along three crystallographic directions, [001], [010] and [100], were carried out as a function of the applied field (0–56 kOe) at various temperatures (∼5–320 K). The magnetic field (H)–temperature (T) phase diagrams were constructed for theGd5(Si1.95Ge2.05) single crystal with field along the t...
متن کامل